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ree bis(4-oligoethyleneoxyphenyl) viologen bistosylate salts of different lengths were prepared via the Zincke reaction followed by a metathesis reaction with silver tosylate, and their chemical structures confirmed by 1H, 13C nuclear magnetic resonance (NMR), Fourier transform infrared (FTIR) techniques, and elemental analysis. Thermogravimetric analysis (TGA) showed these salts had excellent thermal stabilities, losing just 5 % of their initial mass between 283 and 288 °C. Liquid crystalline phases and transition temperatures were determined by differential scanning calorimetry (DSC), polarizing optical microscopy (POM), and variable temperature X-ray diffraction (VTXRD) techniques. The salts exhibited weak fluorescent emission in dichloromethane and no emission in acetonitrile but exhibited light emission in the solid state. Their absolute quantum yields ranged between 3 and 12 %. Impedance spectroscopy showed that the ionic conductivity of the salts increases with the number of oxyethylene units in the extended viologen moiety. The salt-containing four oxyethylene units at each end reach a conductivity value of 10-2 S·cm−1, attributed to its larger molecular flexibility and improved ionic liquid mobility.